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While the Cumberland sample may contain longer chains of fatty acids, SAM is not designed to detect them. But SAM’s ability to spot these larger molecules suggests it could detect similar chemical signatures of past life on Mars if they’re present, Williams said.
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“Curiosity is not a life detection mission,” Freissinet said. “Curiosity is a habitability detection mission to know if all the conditions were right … for life to evolve. Having these results, it’s really at the edge of the capabilities of Curiosity, and it’s even maybe better than what we had expected from this mission.”
Before sending missions to Mars, scientists didn’t think organic molecules would be found on the red planet because of the intensity of radiation Mars has long endured, Glavin said.
Curiosity won’t return to Yellowknife Bay during its mission, but there are still pristine pieces of the Cumberland sample aboard. Next, the team wants to design a new experiment to see what it can detect. If the team can identify similar long-chain molecules, it would mark another step forward that might help researchers determine their origins, Freissinet said.
“That’s the most precious sample we have on board … waiting for us to run the perfect experiment on it,” she said. “It holds secrets, and we need to decipher the secrets.”
Briony Horgan, coinvestigator on the Perseverance rover mission and professor of planetary science at Purdue University in West Lafayette, Indiana, called the detection “a big win for the whole team.” Horgan was not involved the study.
“This detection really confirms our hopes that sediments laid down in ancient watery environments on Mars could preserve a treasure trove of organic molecules that can tell us about everything from prebiotic processes and pathways for the origin of life, to potential biosignatures from ancient organisms,” Horgan said.
Dr. Ben K.D. Pearce, assistant professor in Purdue’s department of Earth, atmospheric, and planetary sciences and leader of the Laboratory for Origins and Astrobiology Research, called the findings “arguably the most exciting organic detection to date on Mars.” Pearce did not participate in the research.
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Curiosity has maintained pristine pieces of the Cumberland sample in a “doggy bag” so that the team could have the rover revisit it later, even miles away from the site where it was collected. The team developed and tested innovative methods in its lab on Earth before sending messages to the rover to try experiments on the sample.
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In a quest to see whether amino acids, the building blocks of proteins, existed in the sample, the team instructed the rover to heat up the sample twice within SAM’s oven. When it measured the mass of the molecules released during heating, there weren’t any amino acids, but they found something entirely unexpected.
An intriguing detection
The team was surprised to detect small amounts of decane, undecane and dodecane, so it had to conduct a reverse experiment on Earth to determine whether these organic compounds were the remnants of the fatty acids undecanoic acid, dodecanoic acid and tridecanoic acid, respectively.
The scientists mixed undecanoic acid into a clay similar to what exists on Mars and heated it up in a way that mimicked conditions within SAM’s oven. The undecanoic acid released decane, just like what Curiosity detected.
Each fatty acid remnant detected by Curiosity was made with a long chain of 11 to 13 carbon atoms. Previous molecules detected on Mars were smaller, meaning their atomic weight was less than the molecules found in the new study, and simpler.
“It’s notable that non-biological processes typically make shorter fatty acids, with less than 12 carbons,” said study coauthor Dr. Amy Williams, associate professor of geology at the University of Florida and assistant director of the Astraeus Space Institute, in an email. “Larger and more complex molecules are likely what are required for an origin of life, if it ever occurred on Mars.”
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